Bis(tetra-n-butylammonium) bis(5,6-dicyanopyrazine-2,3-dithiolato-κ2 S,S′)palladium(II)
نویسندگان
چکیده
In the title complex, (C(16)H(36)N)(2)[Pd(C(6)N(4)S(2))(2)], the centrosymmetric dianion is planar, with an r.m.s. deviation of 0.034 (8) Å. The Pd(II) atom, lying on an inversion center, has a square-planar coordination geometry, with Pd-S bond lengths of 2.276 (3) and 2.294 (3) Å.
منابع مشابه
Tetra-n-butylammonium bis(2,2-dicyanoethylene-1,1-dithiolato)palladium(II)
In the title compound, (C(16)H(36)N)(2)[Pd(C(4)N(2)S(2))(2)], the Pd(II) center adopts a distorted square-planar geometry due to the four-membered chelate rings formed by coordination of the 2,2-dicyano-ethyl-ene-1,1-dithiol-ate (i-mnt) ligands [bite angle 75.0159 (17)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.
متن کاملTetra-n-butylammonium bis(1,1-dicyanoethylene-2,2-dithiolato)platinum(II)
In the title compound, (C(16)H(36)N)(2)[Pt(C(4)N(2)S(2))(2)], the Pt(II) center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano-ethyl-ene-2,2-dithiol-ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system.
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متن کاملBis(tetrabutylammonium) bis(3,4,5-trioxocyclopent-1-ene-1,2-dithiolato-κ2 S,S′)cadmate(II) 0.25-hydrate
The title compound, (C(16)H(36)N)(2)[Cd(C(5)O(3)S(2))(2)]·0.25H(2)O, contains two disordered tetra-butyl-ammonium cations, a complex [Cd(C(5)O(3)S(2))(2)](2-) anion and a 0.25-hydrate water. The anion is composed of a bidentate coordinated 3,4,5-trioxocyclo-pent-1-ene-1,2-dithiol-ate (dtcroc) group forming a distorted tetra-hedral configuration around the Cd(II) ion. The dihedral angle between ...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012